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碱性H2O2处理对杨木P-RC APMP电荷特性的影响

Effect of Alkaline Peroxide Treatment on the Charge Characteristics of Aspen P-RC APMP

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【作者】 郭延柱傅英娟高继水秦梦华张凤山李建华

【Author】 GUO Yan-zhu1 FU Ying-juan1,2 GAO Ji-shui1 QIN Meng-hua1 ZHANG Feng-shan2 LI Jian-hua2(1.Key Lab of Pulp and Paper Science and Technology of Ministry of Education,Shandong Institute of Light Industry,Ji’nan,Shandong Province,250353;2.Huatai Group Co.,Ltd.,Dongying,Shandong Province,257335)

【机构】 山东轻工业学院制浆造纸科学与技术省部共建教育部重点实验室华泰集团有限公司

【摘要】 研究了杨木P-RC APMP在制浆过程中碱性H2O2处理对浆料电荷特性的影响,探讨了酸性基团的引入对纤维润胀及磨浆性能的影响。结果表明,随着NaOH和H2O2用量的增加、处理温度的提高以及处理时间的延长,浆料的羧基含量、表面电荷以及可溶解电荷均呈增加的趋势。在NaOH用量2%、H2O2用量3%、温度80℃的条件下处理90min,P-RC APMP浆料的羧基含量和表面电荷分别增加了31%和25%。纤维电荷的增加有利于纤维润胀能力的提高以及磨浆性能的改善。研究同时发现,磨浆作用会明显增加浆料的表面电荷量,但对浆料的羧基含量影响不大。

【Abstract】 The effects of alkaline peroxide treatment on the charge characteristics of aspen P-RC APMP were studied in this paper,and the influence of the production of new acid groups on the swelling and refinability of the pulp was also evaluated.The results showed that the carboxyl content,surface charge,and dissolved charge of the pulp increased with increasing sodium hydroxide,peroxide,elevating the reaction temperature and extending the reaction time.The carboxyl content and surface charge of P-RC APMP fiber increased 31% and 25% respectively when the dosages of NaOH and H2O2 were 2% and 3%,the reaction time and temperature were 90 min and 80℃ respectively.The increased charge groups in the pulp were beneficial to the fiber swelling and pulp refinability.It was also found that refining could result in the increase of the fiber surface charge,but had no significant effect on the carboxyl content of the pulp.

【基金】 国家教育部新世纪优秀人才支持计划(NCET-08-0882);国家自然科学基金(30972327,20576065)的资助
  • 【文献出处】 中国造纸 ,China Pulp & Paper , 编辑部邮箱 ,2010年07期
  • 【分类号】TS743.3
  • 【被引频次】5
  • 【下载频次】111
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