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增塑增韧聚丙烯的制备及其性能研究

Research on Preparation and Properties of Plasticized and Toughened Polypropylene

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【作者】 周中玉潘泳康唐颂超王庆海

【Author】 ZHOU Zhongyu,PAN Yongkang,TANG Songchao,WANG Qinghai(Key Lab for Ultrafine Materials of Ministry of Education,College of Materials Science and Engineering,East China University of Science and Technology,Shanghai 200237,China)

【机构】 华东理工大学材料科学与工程学院超细材料制备与应用教育部重点实验室

【摘要】 以液体石蜡作为聚丙烯(PP)的增塑剂,首先将纳米二氧化硅(SiO2)预先分散于液体石蜡中制成纳米溶胶,然后采用双螺杆挤出机将此溶胶与PP熔融共混制备了增塑增韧PP复合材料,研究了液体石蜡和纳米SiO2对PP力学性能和结晶性能的影响。结果表明,经过液体石蜡增塑后,PP的冲击强度可提高90%;再经过纳米SiO2增韧后,其冲击强度可进一步提高100%;液体石蜡能够提高PP的结晶度,纳米SiO2能够减小PP的球晶尺寸。

【Abstract】 Nano silicon dioxide(nano-SiO2) was dispersed into liquid paraffin(LP) forming a nano-sol,which was melt blended with PP using a twin-screw extruder resulting in PP composites.The effect of LP and nano-SiO2 content on mechanical properties and crystallization behavior of PP was investigated.By the plasticization and toughening of LP and nano-SiO2,the impact strength of PP composites was 190 % higher than that of neat PP.In addition,it was found that LP increased the crystallinity of PP and nano-SiO2 decreased the spherulite size.

  • 【分类号】TQ325.14
  • 【被引频次】16
  • 【下载频次】395
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