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CPVC/ABS/CPE三元共混体系的组成与性能关系研究

Study on the Relationship Between Compositions and Properties of CPVC/ABS/CPE Ternary Blends

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【作者】 马军袁茂全牟南翔胡妹华王建武德珍

【Author】 MA Jun1,YUAN Maoquan2,MU Nanxiang1, HU Meihua2,WANG Jian2,WU Dezhen1*(1.State Key Laboratory of Chemical Resource Engineering,College of Materials Science & Engineering, Beijing University of Chemical Technology,Beijing 100029,China; 2.Shanghai Chlor-Alkli Chemical Company,Shanghai 200241,China)

【机构】 北京化工大学材料科学与工程学院化工资源有效利用国家重点实验室上海氯碱化工股份有限公司

【摘要】 研究了氯化聚氯乙烯(CPVC)、丙烯腈-丁二烯-苯乙烯共聚物(ABS)和氯化聚乙烯(CPE)三元共混体系的组成与性能之间的关系。结果表明,ABS树脂可以有效降低CPVC/ABS/CPE三元共混体系的平衡扭矩,缩短三元共混体系的塑化时间,改善其流动性;当CPE含量固定、共混体系中CPVC与ABS的质量配为7∶3时,共混体系的拉伸强度和缺口冲击强度达到最佳,共混体系具有较好的综合力学性能;随着CPE含量的增加,三元共混体系的缺口冲击强度显著提高,CPE对三元共混体系具有优良的增韧作用,用量以15份为宜。

【Abstract】 In this paper,the relationship between compositions and properties of chlorinated poly(vinyl chloride)/acrylonitrile-butadiene-styrene copolymer/chlorinated polyethylene(CPVC/ABS/CPE) ternary blends was studied.The torque of CPVC/ABS/CPE decreased and thus the plasticizing time was reduced significantly with increasing content of ABS.When the weight ratio of CPVC to ABS was 7∶3,the CPVC/ABS/CPE ternary blends displayed the best mechanical properties.CPE had good toughening effects on CPVC/ABS/CPE ternary blends,and the optimum dosage was 15 phr.

【基金】 国家支撑计划资助项目(2007BAE50B02)
  • 【分类号】TQ325.3
  • 【被引频次】10
  • 【下载频次】219
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