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水溶液中对叔辛基酚的紫外光降解研究

UV photodegradation of p-tert-octyl phenol(4-OP) in water

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【作者】 吴彦霖余焱袁海霞董文博

【Author】 WU Yan-lin,YU Yan,YUAN Hai-xia,DONG Wen Bo(Department of Environmental Science and Engineering,Fudan University,Shanghai 200433,China)

【机构】 复旦大学环境科学与工程系

【摘要】 研究了185nm紫外光对薄液层中对叔辛基酚(4-OP)的作用规律,考察了初始浓度、液层厚度、光强等因素对4-OP的降解效果的影响.结果表明,用该方法降解水中4-OP,在4-OP初始浓度10mg/L,液层厚度为2mm,光照距离为10cm,光照45min后,去除率可达到95%以上,其降解过程符合表观一级反应动力学特征.

【Abstract】 The degradation of p-tert-octyl phenol (4-OP) in a thin aqueous layer by 185 nm UV irradiation and its dependence on the initial concentration,thickness of the aqueous layer and light intensity were investigated. The 185 nm UV irradiation was proved to be effective for the removal of 4-OP in water. The rate of degradation was increased to more than 95% after the illumination for 45min when the initial concentration was 10mg/L,the thickness of the aqueous layer was 2mm and the distance from UV lamp was 10cm. The degradation reaction was found to accord with the characteristic of apparent first-order reaction.

【关键词】 185nm紫外光降解对叔辛基酚
【Key words】 185nm UVdegradation4-OP
  • 【文献出处】 中国环境科学 ,China Environmental Science , 编辑部邮箱 ,2010年10期
  • 【分类号】TU991.2
  • 【被引频次】12
  • 【下载频次】220
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