Synthesis and characterization of Ce_0.8Sm_0.2O_1.9 nanopowders using an acrylamide polymerization process

【摘要】 Ce0.8Sm0.2O1.9(SDC) nanopowders were synthesized by an acrylamide polymerization process.The XRD results showed that SDC powders prepared at 700 °C possessed a cubic fluorite structure.Transmission electron microscopy(TEM) indicated that the particle sizes of powders were in the range of 10-15 nm.A 98.3% of theoretical density was obtained when the SDC pellets were sintered at 1350 °C for 5 h,indicating that the powders had good sinterability.The conductivity of the sintered SDC ceramics was 0.019 S/cm at 600 °C and the activation energy was only 0.697 eV.Furthermore,a unit cell was fabricated from the powders and the maximum power density of 0.169 W/cm2 was achieved at 700 °C with humidified hydrogen as the fuel and air as the oxidant.更多还原

【Abstract】 Ce0.8Sm0.2O1.9(SDC) nanopowders were synthesized by an acrylamide polymerization process.The XRD results showed that SDC powders prepared at 700 °C possessed a cubic fluorite structure.Transmission electron microscopy(TEM) indicated that the particle sizes of powders were in the range of 10-15 nm.A 98.3% of theoretical density was obtained when the SDC pellets were sintered at 1350 °C for 5 h,indicating that the powders had good sinterability.The conductivity of the sintered SDC ceramics was 0.019 S/cm at 600 °C and the activation energy was only 0.697 eV.Furthermore,a unit cell was fabricated from the powders and the maximum power density of 0.169 W/cm2 was achieved at 700 °C with humidified hydrogen as the fuel and air as the oxidant.更多还原