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原位接枝改性炭黑补强NR结构与性能的研究

Study on structure and properties of NR reinforced by in-situ grafted carbon black

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【作者】 王雪飞周志诚周淑华杨军张立群

【Author】 WANG Xue-fei1,2,ZHOU Zhi-cheng1,ZHOU Shu-hua1,YANG Jun1,ZHANG Li-qun2(1.Zhuzhou Times New Materials Science and Technology Co.,Ltd,Zhuzhou 412007,China;2.Beijing University of Chemical Tech-nology,Beijing 100029,China)

【机构】 株洲时代新材料科技股份有限公司北京化工大学材料科学与工程学院

【摘要】 研究原位接枝改性炭黑补强NR的物理性能和动态力学性能,并分别采用热重分析仪、傅立叶红外光谱仪及转矩流变仪对原位接枝改性炭黑补强NR的结构进行表征和研究。结果表明,炭黑原位接枝改性后与橡胶界面的相互作用增强,硫化胶的性能提高,改性剂用量为4.5份时硫化胶的综合性能最好;改性剂与橡胶和炭黑发生了接枝反应,并参与了硫化。

【Abstract】 The physical properties and dynamic property of NR reinforced by in-situ grafted carbon black were investigated,and the structure of compound was characterized and analyzed by using FTIR,TG and torque rheometer.The results showed that,when carbon black was in-situ grafted,the interaction between carbon black and NR was strengthened,the properties of vulcanizate were improved;the comprehensive performance of vulcanizate was the best when the addition level of modifier was 4.5 phr;the modifier was grafted onto NR and carbon black,and participated in the vulcanization.

【关键词】 NR炭黑原位接枝改性
【Key words】 NRcarbon blackin-situ graftingmodification
  • 【文献出处】 橡胶工业 ,China Rubber Industry , 编辑部邮箱 ,2010年01期
  • 【分类号】TQ330.15
  • 【被引频次】3
  • 【下载频次】297
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