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不同形貌的Cu2O:可控合成及光学性质(英文)

Cu2O with Different Morphologies:Controlled Synthesis and Optical Properties

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【作者】 尚通明关明云孙建华周全法徐正

【Author】 SHANG Tong-Ming1,2 GUAN Ming-Yun1,2 SUN Jian-Hua1,2 ZHOU Quan-Fa1 XU Zheng*,2(1Jiangsu Key Laboratory of Precious Metals Chemistry,School of Chemistry and Engineering,Jiangsu Teachers University of Technology,Changzhou Jiangsu 213001)(2State Key Laboratory of Coordination Chemistry,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210093)

【机构】 江苏省贵金属深加工技术及其应用重点实验室江苏技术师范学院化学化工学院南京大学配位化学国家重点实验室,南京大学化学化工学院

【摘要】 Cuprous oxide(Cu2O) hexapodal branch structure with high uniformity was prepared by a solution phase route using sodium dodecyl sulfate as a capping agent.The shapes of Cu2O crystal(flower-like structure,nanocube and nanoplate) were tuned by varying species and concentrations of surfactants to control the growth rate on different crystal planes of Cu2O.Cu2O nanostructures were characterized by UV-Vis spectroscopy,XRD,TEM and SEM.XRD result shows that the obtained Cu2O belongs to cubic phase.TEM and SEM results demonstrate that specie and concentration of surfactants play a key role in the formation of various morphologies of Cu2O.The formation mechanism is discussed.Moreover,the optical properties of the obtained Cu2O are shape-dependent.

【Abstract】 Cuprous oxide(Cu2O) hexapodal branch structure with high uniformity was prepared by a solution phase route using sodium dodecyl sulfate as a capping agent.The shapes of Cu2O crystal(flower-like structure,nanocube and nanoplate) were tuned by varying species and concentrations of surfactants to control the growth rate on different crystal planes of Cu2O.Cu2O nanostructures were characterized by UV-Vis spectroscopy,XRD,TEM and SEM.XRD result shows that the obtained Cu2O belongs to cubic phase.TEM and SEM results demonstrate that specie and concentration of surfactants play a key role in the formation of various morphologies of Cu2O.The formation mechanism is discussed.Moreover,the optical properties of the obtained Cu2O are shape-dependent.

【基金】 国家自然科学基金资助项目(No.90606005,20490210);江苏省高校自然科学基金(No.08KJD150003);常州市青年基金(No.CQ2008011)项目资助
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2010年07期
  • 【分类号】O614.121
  • 【被引频次】15
  • 【下载频次】405
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