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放电等离子烧结制备锑掺杂氧化锡陶瓷研究

Fabrication of Antimony Doped Tin Oxide Ceramics by Spark Plasma Sintering Technique

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【作者】 张建荣徐秀娟李秀花高濂孙静

【Author】 ZHANG Jian-Rong,1,2 XU Xiu-Juan1 LI Xiu-Hua1 GAO Lian2 SUN Jing2 (1Department of Chemistry, Key Laboratory for Advanced Materials of Ministry of Education East China University of Science and Technology, Shanghai 200237) (2Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050)

【机构】 华东理工大学化学系教育部结构可控先进功能材料及其制备重点实验室中国科学院上海硅酸盐研究所

【摘要】 <正>透明导电氧化物材料(Transparent Conductive Oxides,TCOs)由于具有高达105S·cm-1的电导率,可见光区域具有80%以上的透过率而在光电子、显示器件、太阳能电池、智能窗领域具有广泛的应用。如向In2O3中添加Sn元素(IndiumTinOxide,ITO),

【Abstract】 Antimony doped tin oxide(ATO) nanoparticles with specific surface area of 58.7 m2·g-1 and low degree of agglomeration were synthesized by hydrothermal and post calcination method. Using this ATO as starting material, ATO ceramics with relative density of 97.4% and resistivity of 0.004 64 Ω·cm-1 were fabricated by Spark Plasma Sintering(SPS) Technique at 850 ℃. XRD patterns of the ATO ceramics show that the 800 ℃ sintered pellet exhibits (211) preferred orientation. SEM micrographs also show that the morphology of the ATO grains changes with increasing in sintering temperature. Further increase in sintering temperature to 900 ℃ will result in the reduction of the ATO to metal tin.

【基金】 教育部博士点新教师基金(No.200802511022)资助项目
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2010年06期
  • 【分类号】TQ174.65
  • 【被引频次】6
  • 【下载频次】198
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