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基于1,5,9-三硒杂[9]二茂铁环蕃的一维链状汞(Ⅱ)配位聚合物的合成与晶体结构(英文)
Synthesis and Crystallographic Study of 1D Mercury(Ⅱ) Coordination Polymer of 1,5,9-Triselena[9]ferrocenophane
【摘要】 Amercury(Ⅱ)coordinationpolymerwith1,5,9-triselena[9]ferrocenophane(L),[HgI2L·0.5C4H4O·0.5CH3OH]n, has been synthesized and characterized. The X-ray crystal structure shows that bridging by the ligand L causes compound to form one-dimensional chain. The half-wave potential of 1,1′-ferrocenylene group is more negative than that of the "free" ligand, which reveals no through-space interaction Hg…Fe in the coordination polymers.
【Abstract】 Amercury(Ⅱ)coordinationpolymerwith1,5,9-triselena[9]ferrocenophane(L),[HgI2L·0.5C4H4O·0.5CH3OH]n, has been synthesized and characterized. The X-ray crystal structure shows that bridging by the ligand L causes compound to form one-dimensional chain. The half-wave potential of 1,1′-ferrocenylene group is more negative than that of the "free" ligand, which reveals no through-space interaction Hg…Fe in the coordination polymers.
【Key words】 Mercury(Ⅱ)； 1,5,9-Triselena[9]ferrocenophane； coordination polymer；
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2010年02期
- 【分类号】O631.3
- 【被引频次】3
- 【下载频次】128