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双端氨基(聚)酰胺酸扩链的聚氨酯弹性体的合成、结构和性能
The synthesis,structure and properties of PU elastomer with(poly) imide acids as extender
【摘要】 合成了3种不同相对分子质量的双端氨基(聚)酰胺酸,且以此和3,3′-二氯-4,4′-二氨基-二苯基甲烷(MOCA)为扩链剂,分别制备了聚氨酯弹性体,并对该系列进行了表征,研究了其性能和微相分离情况。结果表明,以(聚)酰胺酸为扩链剂合成的聚氨酯弹性体具有明显的微相分离结构,并具有较好的耐热性和机械性能。
【Abstract】 In this study,three kinds of double-amino end-capping(poly)imide acids with different molecular weights were synthesized.These(poly)amide acids were used with Moca as chain extender to prepare the PU elastomers.This series of elastomer were characterized.Properties and micro-phase separation were investigated.The results showed that the PU with(poly)imide acids as extender had a clear structure of micro-phase separation and good thermal stability and mechanical properties.
【关键词】 双端氨基(聚)酰胺酸;
扩链剂;
聚氨酯弹性体;
微相分离;
性能;
【Key words】 double-amino end-capping(poly)imide acids; chain extender; PU; micro-phase separation; property;
【Key words】 double-amino end-capping(poly)imide acids; chain extender; PU; micro-phase separation; property;
【基金】 中国船舶工业集团公司重点资助项目
- 【文献出处】 弹性体 ,China Elastomerics , 编辑部邮箱 ,2010年01期
- 【分类号】TQ334.1
- 【下载频次】331