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凹凸棒石吸附地下水中的Fe3+研究

Adsorption of Fe3+ from groundwater by using palygorskite

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【作者】 赵金秋韩丽丽马福英张秀丽

【Author】 Zhao Jinqiu,Han Lili,Ma Fuying,Zhang Xiuli(School of Material Sciences and Technology,China University of Geosciences,Beijing 100083,China)

【机构】 中国地质大学材料科学与工程学院

【摘要】 凹凸棒石是一种含水,富镁、富铝的硅酸盐黏土矿物,由相互平行的硅氧四面体双链组成,比表面积大,具有良好的吸附性能。通过静态实验,探讨了凹凸棒石吸附水中Fe3+时的影响因素。结果表明,在Fe3+浓度为20.00mg/L时,使用2.00g凹凸棒石、水浴温度为30℃、初始pH值为4至5、吸附40min后对水中Fe3+的去除率最大。另外,研究表明,Fe3+去除率随吸附时间的增加呈曲线变化,随凹凸棒石样品的用量的增加有所增加,随pH的增加明显增加,随着温度升高影响不大。根据吸附等温线知,凹凸棒石吸附Fe3+的规律较好地满足Langmuir吸附等温式。

【Abstract】 Palygorskite is a silicate clay mineral which has rich magnesium,and aluminum,by the parallel composition of siliconoxygen tetrahedron duplexes,specific surface area,and has good adsorption properties.This paper discusses the factors of Fe3+adsorption by the static experiments.The results show when the concentration of Fe3+solution is 20.00mg.L-1,using 2.00grams of palygorskite,bathing 30℃of water tem-perature,having 4~5of initial pH value,oscillating of 40minutes,the maximum removal rate of Fe3+from water is the largest.In addition,the study shows that removal rate of Fe3+showed a curvilinear shape when the adsorption time increased,increased with the amount of palygorskite increased,increased with the increase of pH,and had little effect with the increase of temperature.According to known adsorption isotherms,paly-gorskite’s adsorption of Fe3+can well meet the law of Langmuir adsorption isotherm.

【关键词】 凹凸棒石吸附铁离子
【Key words】 palygorskiteadsorptionFe3+
  • 【文献出处】 实验技术与管理 ,Experimental Technology and Management , 编辑部邮箱 ,2010年08期
  • 【分类号】TB383.1
  • 【被引频次】5
  • 【下载频次】192
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