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有序介孔碳用于吸附水相中的氯代芳香族化合物

Ordered mesoporous carbon adsorb the chloranated aromatric compounds from aqueous phase

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【作者】 崔祥婷闻振涛万颖

【Author】 CUI Xiang-ting,WEN Zhen-tao,WAN Ying(College of Life and Environment Sciences,Shanghai Normal University,Shanghai 200234,China)

【机构】 上海师范大学生命与环境科学学院

【摘要】 以三嵌段共聚物聚环氧乙烯-聚环氧丙烯-聚环氧乙烯(F127)为结构导向剂,甲阶酚醛树脂为碳前驱体,通过溶剂挥发诱导自组装(EISA)的方法制备介孔碳材料,通过X射线衍射(XRD),氮气吸脱附分析表征其结构及性质.将该材料用于去除水相中对氯苯酚和对氯苯胺,表现出很好的吸附性能,其饱和吸附量分别达到220mg/g和210mg/g,与活性炭相比较,在污染物浓度较低时显示出更优越的吸附能力.

【Abstract】 The ordered mesoporous carbon was synthesized with triblock copolymer F127 as the structure directing agent,low-polymerized phenolic resins as carbon sources via the evaporation induced self-assembly route.Small angle X-ray diffraction and nitrogen sorption techniques proved the structure and characters of the material.To remove p-chlorophenol and p-chloroaniline from their aqueous solution,the mesoporous carbon showed great adsorbed ability,with the saturated adsorbed amounts as high as 220 mg/g and 210 mg/g,respectively,showing superiority over the autiqated carbon at very low concentration of contaminants.

【关键词】 有序介孔水相吸附
【Key words】 orderedmesoporousaqueous phaseadsorption
  • 【文献出处】 上海师范大学学报(自然科学版) ,Journal of Shanghai Normal University(Natural Sciences) , 编辑部邮箱 ,2010年03期
  • 【分类号】X703
  • 【被引频次】16
  • 【下载频次】289
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