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TiO2/ZnO纳米光催化剂的制备及性能研究

Preparation and properties of TiO2/ZnO Photocatalyst

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【作者】 徐青吕伟

【Author】 XU Qing,Lü Wei(School of Chemistry and Chemical Engineering,Shandong University,Jinan 250100,China)

【机构】 山东大学化学与化工学院

【摘要】 通过二步法(阳极氧化法和水热法)得到结构规则、有序核-壳结构的TiO2/ZnO纳米复合材料,并利用SEM、UV-vis、TEM等方法对所制备的纳米复合材料进行了表征。以甲基橙为目标降解物,自然光为光源,研究了TiO2/ZnO纳米光催化剂的光催化活性。结果表明,TiO2/ZnO复合光催化剂能提高对太阳光的利用率,发现在降解液pH值为3、太阳光催化降解5 h时,催化剂的降解效果最好,降解率达90%。

【Abstract】 Highly ordered TiO2/ZnO nanocomposites with core-shell structure were successfully fabricated by a two-step method(anodic oxidation and hydrothermal method).The nanocomposites were analyzed by means of a scanning electron microscope(SEM),double beam UV-vis spectrophotometer and transmission electron microscope(TEM).The photocatalytic activity of the prepared material was tested by taking methyl orange as a pollutant on the model and natural light as the light source.The results showed that,TiO2/ZnO composite photocatalyst could improve the utilization of sunlight,and could show the best catalytic activity under the condition of pH=3 solution and degraded under the sun for 5 hours,which reached to 90%.

【关键词】 二步法光催化活性TiO2/ZnO甲基橙
【Key words】 two-step methodphotoactivityTiO2/ZnOmethyl orange
【基金】 山东省自然科学基金资助项目(Y2008G25);济南市高校自主创新资助项目(200815063)
  • 【文献出处】 山东大学学报(工学版) ,Journal of Shandong University(Engineering Science) , 编辑部邮箱 ,2010年04期
  • 【分类号】O643.36
  • 【被引频次】15
  • 【下载频次】466
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