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烷基羧酸钠的蠕虫状胶束流变性研究

Studies on rheological properties of wormlike micelles formed by sodium carboxylate

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【作者】 于丽孙焕泉肖建洪陈辉纪永强郑利强李干佐

【Author】 YU Li1,2,SUN Huan-quan3,XIAO Jian-hong1,CHEN Hui1, JI Yong-qiang2,ZHENG Li-qiang2,LI Gan-zuo2(1.Gudao Oil Recovery Plant,Shengli Oil Field,Sinopec,Dongying 257231,Shandong,China;2.Key Laboratory of Colloid and Interface Chemistry of Ministry of Education,Shandong University,Jinan 250100,Shandong,China;3.Shengli Oil Field,Sinopec,Dongying 257000,Shandong,China)

【机构】 中国石化股份胜利油田分公司孤岛采油厂山东大学胶体与界面化学教育部重点实验室中国石化股份胜利油田分公司

【摘要】 针对油田开发实际,研究了温度、醇、烷烃、无机盐、油田水质矿化度、聚合物等因素对烷基羧酸钠——油酸钠(NaOA)在磷酸钠(Na3PO4)存在条件下形成的蠕虫状胶束流变性质的影响。不仅从理论上对蠕虫状胶束的零剪切粘度、剪切活化能等流变性质进行了分析和解释,而且为拓宽阴离子蠕虫状胶束在石油开采领域的应用提供了依据。

【Abstract】 The effects of various factors on rheological properties of wormlike micelles formed by sodium carboxylate,namely sodium oleate(NaOA) aqueous solution in the presence of trisodium phosphate(Na3PO4) were investigated.These factors include temperature,alcohols,alkane,inorganic salts,the mineralization of oil field water and polymes,which are frequently encountered in the oilfield development process.The rheological properties of wormlike micelles,such as zero shear viscosity and shear activation energy were analyzed and explained.These studies provide the basis of applications of wormlike micelles to oilfields.

【基金】 国家“十一五”支撑计划资助项目(2007BAE52B052);中国博士后科学基金资助项目(20080441156);山东省科技攻关资助项目(2006GG2206004,2009GG10003027);山东省博士后创新专项基金资助项目(200701005)
  • 【文献出处】 山东大学学报(理学版) ,Journal of Shandong University(Natural Science) , 编辑部邮箱 ,2010年01期
  • 【分类号】O648.1
  • 【被引频次】7
  • 【下载频次】438
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