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Fenton-UASB-生物接触氧化处理Fischer-Tropsch合成废水的研究

Study on Fischer-Tropsch synthesis waste water treatment by Fenton-UASB-Biological contact oxidation

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【作者】 吴丽任云霞董桂燕刘黎李永旺

【Author】 WU Li1,2,REN Yun-xia1,DONG Gui-yan1,LIU Li1,LI Yong-wang1 (1.Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan 030001,China;2.Graduate University of Chinese Academy of Sciences,Beijing 100049)

【机构】 中国科学院山西煤炭化学研究所中国科学院研究生院

【摘要】 用Fenton-UASB-生物接触氧化组合工艺对Fischer-Tropsch合成废水进行处理。实验结果表明,采用Fenton法对废水进行预处理,在pH值为3,H2O2的投加量为30 mL/L,Fe2+投加量为1.2 g/L,反应时间为120 min时,去除了63%的CODCr,有效地提高了废水的可生化性;Fenton预处理出水经UASB厌氧生物处理后,CODCr去除率达90%以上;最后经接触氧化后,出水CODCr达100 mg/L以下,达到了GB8978-1996《污水综合排放标准》中化工类废水的二级排放标准。

【Abstract】 The waste water from Fischer-Tropsch synthesis plant was treated by Fenton-UASB-Biological contact oxidation combined process.The results showed that the pretreatment of the waste water by Fenton oxidation can not only eliminate CODCr by 63%,but also improve its bio-degradability effectively when the pH was 3,reaction time were 120 min and dosage of H2O2 and Fe2+ was 30 mL/L and 1.2 g/L respectively;after treatment by UASB anaerobic,the CODCr removal rate could reach up to 90%;and finally after contact oxidation,the effluent CODCr was below 100 mg/L,which can meet the second discharge standard of chemical waste water in GB8978-1996 Integrated Wastewater Discharge Standard.

【关键词】 Fischer-Tropsch合成FentonUASB接触氧化
【Key words】 Fischer-Tropsch synthesisFentonUASBcontact oxide
【基金】 国家自然科学基金(25060361/B01)
  • 【文献出处】 燃料化学学报 ,Journal of Fuel Chemistry and Technology , 编辑部邮箱 ,2010年04期
  • 【分类号】X703
  • 【被引频次】9
  • 【下载频次】134
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