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人造含硼金刚石单晶表面形貌与生长机制研究

Surface Morphology and Growth Mechanism of the Synthetic Boron-doped Diamond Single Crystals

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【作者】 宫建红李木森王美亓永新阮立群高军

【Author】 GONG Jian-hong1,2,3,LI Mu-sen3,4,WANG Mei3,4,QI Yong-xin3,4,RUAN Li-qun5,GAO Jun1(1.School of Mechanical & Electrical Engineering,Shandong University at Weihai,Weihai 264209,China;2.School of Mechanical Engineering,Shandong University,Jinan 250061,China;3.Shandong Engineering Research Centre for Superhard Materials,Zoucheng 273500,China;4.School of Material Science & Engineering,Shandong University,Jinan 250061,China;5.Department of Mechanical Engineering and Science,Kumamoto University,Kumamoto 8608555,Japan)

【机构】 山东大学威海分校机电工程学院山东大学机械工程学院山东省超硬材料工程技术研究中心山东大学材料科学与工程学院熊本大学自然科学研究科机械系统

【摘要】 本文借助Olympus光学显微镜、扫描电子显微镜(SEM)和原子力显微镜(AFM)对高温高压合成的含硼金刚石单晶表面形貌进行了分析。研究发现,含硼金刚石表面存在蚀坑、球形颗粒集团、平行台阶、花瓣状生长丘和三角形螺旋台阶等多种表面形貌。这些形貌与晶体内部的缺陷有关,硼原子的进入使金刚石晶体生长速度增加,位错增多,进而导致不同表面形貌的形成,螺旋位错生长是含硼金刚石的主要生长方式。

【Abstract】 The surface morphology of the boron-doped diamond single crystals was analyzed by means of Olympus optical microscope,scanning electronic microscope(SEM) and atom force microscopy(AFM).Various features are found on the crystal surfaces of the boron-doped diamond such as pits,spherical clusters,parallel steps,petal-like knobs and triangle spiral steps,which distinguish to those on the surface of plain diamonds.These features are concerning to the dislocations of the crystal lattices.The boron atoms accelerate the diamond growth and increase the dislocation.It is demonstrated that the screw dislocation growth pattern should be the main growth mechanism of the boron-doped diamond.

【基金】 国家自然科学基金(No.50772060);山东省博士后创新项目专项基金(No.200702024)
  • 【文献出处】 人工晶体学报 ,Journal of Synthetic Crystals , 编辑部邮箱 ,2010年01期
  • 【分类号】TQ164
  • 【被引频次】20
  • 【下载频次】288
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