【摘要】 以α-吡啶甲酸为配体,运用溶剂挥发法,合成了一种超分子配合物α-吡啶甲酸铜{Cu(C5H4NCOO)2.2H2O}m,用红外光谱、紫外-可见光谱对配合物进行了表征,用X-射线单晶衍射测定了配合物的单晶结构.配合物为三斜晶系,P1-(2)空间群,晶胞参数:a=0.51291(11)nm,b=0.76367(17)nm,c=0.9226(2)nm,α=74.914(3)°,β=84.346(3)°,γ=71.463(3),°V=0.33077(44)nm3,Z=1.采用循环伏安法研究了配合物在水溶液中的电化学性质.更多还原

【Abstract】 A new supermolecular copper(Ⅱ) complex with α-picolinic acid was synthesized and characterized by FT-IR and electron spectrum.Its single crystal structure was determined by single crystal X-ray diffraction method.The complex {Cu(C5H4NCOO)2·2H2O}m belongs to triclinic,with space group P1-(2),and the lattice parameters are a=0.51291(11)nm,b=0.76367(17)nm,c=0.9226(2)nm,α=74.914(3)°,β=84.346(3)°,γ=71.463(3)°,V=0.33077(44)nm3,Z=1.The electrochemical activity was studied in water with an electrochemical analyzer.更多还原