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稻壳-聚乙烯复合材料经历自然老化后的性能变化(英文)

Performance of rice-hull-PE composite exposed to natural weathering

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【作者】 王伟宏卜凡华张征明隋淑娟五清文

【Author】 WANG Wei-hong,BU Fan-hua,ZHANG Zheng-ming,SUI Shu-juan,WANG Qing-wen Key Laboratory of Bio-based Material Science & Technology(Ministry of Education),Northeast Forestry University,Harbin 150040,P.R.China.

【机构】 东北林业大学,生物质材料科学与技术教育部重点实验室

【摘要】 稻壳粉被广泛地应用于聚合物复合材料,但对这些复合材料的耐老化性能研究得还很少。本文研究了两种稻壳粉/聚乙烯(RH-PE)复合板经过两年室外自然老化以后的性能变化。试件的抗弯强度和弹性模量没有变化。但在试验结束后试件的亮度增加了23%以上,总色差变化9个单位以上,意味着消费者当初挑选的颜色发生了明显变化。傅立叶红外(FTIR)和X射线光电子能谱(XPS)分析显示,试件表面发生了氧化反应,老化后红色板材产业明显的C=O峰,但黄色板材的C=O峰并没有明显变化。两种板材都显示木素纤维素减少和聚乙烯的无定形区域减少。图7表4参16。

【Abstract】 Rice-hull powder is widely used in manufacturing reinforced plastic composites.However,its weathering ability is rarely considered.We studied the performance of two types of rice-hull-polyethylene(RH-PE) composites after they were exposed outdoor to natural weathering for two years.The samples did not change in bending strength and elasticity modulus.At the end of the testing period,colour lightness had increased by more than 23% and total colour had changed by more than 9 units.This means the colour evidently differentiate from the original colour that the customers choose.The analyses of Fourier-transform infrared(FTIR) and X-ray photoelectron spectroscopy(XPS) showed that oxidation had occurred on sample surfaces.Red lumber presented an obvious C=O peak after weathering,while yellow lumber did not present an obvious peak as evidence of oxidation.Both types of lumbers showed a reduction of lignocellulosic groups and amorphous regions of PE.

【关键词】 稻壳聚乙烯复合材老化
【Key words】 rice-hullpolyethylenecompositesweathering
【基金】 funded by National Natural Science Foundation of China 30671644 and NCET
  • 【文献出处】 Journal of Forestry Research ,林业研究(英文版) , 编辑部邮箱 ,2010年02期
  • 【分类号】TB332
  • 【被引频次】3
  • 【下载频次】153
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