【摘要】 利用溶剂热除水的方法,在冰醋酸中,将二水醋酸锌脱水制备了一种新型的无水醋酸锌.X射线单晶衍射分析揭示出化合物1具有一个四面体形的金属中心,它与顺-反醋酸根阴离子相连接,形成一种三维四连接的网状lvt拓扑结构.更多还原

【Abstract】 A novel anhydrous zinc acetate,(δ-[Zn(CH3COO)2](1),was readily prepared by solvothermal dehydration of zinc acetate dihydrate in glacial acetic acid.X-ray single-crystal analysis reveals that compound 1 consists of tetrahedral metal centers,which are linked by the syn-anti acetato anions forming a three-dimensional(3D) 4-connected net of lvt topology.更多还原