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阳光下二氧化钛-膨润土对SDBS的降解

SOLAR PHOTOCATALYTIC DEGRADATION OF SODIUM DODECYL BENZENE SULFONATE BY TiO2-BENTONITE

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【作者】 温淑瑶陈素云马占青高晓飞王晓岚

【Author】 WEN Shu-yao1,CHEN Su-yun2,MA Zhan-qing3,GAO Xiao-fei1,WANG Xiao-lan1 1.School of Geography,Beijing Normal Univ,Beijing 100875,China;2.Beijing Geotechnical Institute Engineering Consultants LTD,Beijing 100038,China;3.Department of Chemical Engineering,Hangzhou Vocation and Technical College,Hangzhou 310018,China

【机构】 北京师范大学地理学与遥感科学学院北京市勘察设计研究院有限公司杭州职业技术学院化学工程系

【摘要】 实验以阳光照射6h为条件研究0.5‰TiO2-膨润土对水中十二烷基苯磺酸钠(SDBS)的降解过程,结果表明:阳光照射下,TiO2-膨润土复合催化剂去除水中SDBS的性能不仅优于TiO2,而且解决了TiO2颗粒细、难回收再用的问题;且在照射的同一时间段内,阳光中紫外光强度越强,SDBS的去除率越高,即使在北方冬天紫外光强度十分弱的条件下(20μW/cm2~180μW/cm2),TiO2-膨润土复合催化剂仍能6h去除51.1%的SDBS。实验中还发现以太阳光为光源,TiO2-膨润土去除模拟废水中的SDBS的最佳条件是:pH值6.00,TiO2-膨润土的投加量约为0.5‰,模拟废水的初始浓度约为20mg/L,与以紫光灯为光源时的最佳条件相近。

【Abstract】 Solar photocatalytic degradation within 6h of Sodium Dodecyl Benzene Sulfonate(SDBS)in aqueous solution by 0.5‰ TiO2-bentonite was studied.The results showed that:(1)TiO2 was very difficult to be recovered duo to the very small particle size of TiO2.The problem was solved by using TiO2-bentonite.Efficiency of SDBS removal by TiO2-bentonite was higher than that by TiO2 in the natural sunlight.(2)Natural sunlight as light source,the optimum condition that SDBS removal in aqueous solution by TiO2-bentonite was:pH=6.00,dosage of TiO2-bentonite =0.5‰,original concentration of SDBS in aqueous solution =20 mg/L.Above condition was similar to that as using ultraviolet light source.(3)In the same period,the higher the ultraviolet ray intensity of natural sunlight,the more of SDBS removal by TiO2-bentonite,even if ultraviolet ray intensity was very weak(20 μW/cm2~180 μW/cm2),in such case,51.1% SDBS was removed by TiO2-bentonite.

【基金】 国家基础科学人才培养基金项目(J0630532)
  • 【文献出处】 矿物岩石 ,Journal of Mineralogy and Petrology , 编辑部邮箱 ,2010年01期
  • 【分类号】X52
  • 【被引频次】8
  • 【下载频次】173
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