【摘要】 通过盐浴热处理实验,研究了Fe-0.6C二元合金和Fe-0.6C-1M/2M三元合金(质量分数,%,M为Mn和Si)在1073 K下的组织演化和相变动力学.结果表明,Fe-0.6C合金在1073 K保温约5.5 s完成珠光体→奥氏体转变,珠光体中渗碳体先于铁素体转变成奥氏体;添加1%Si减缓了奥氏体化速率,但未改变渗碳体先消失的特征;添加1%—2%Mn略微缩短了奥氏体转变完成时间,但珠光体中渗碳体和铁素体几乎同时完成奥氏体转变.在C扩散控制长大的假设下,奥氏体在单个珠光体片层间的一维长大模拟结果表明,通过改变界面处奥氏体的C浓度,Mn提高奥氏体生长速率而Si减缓奥氏体生长速率,与奥氏体化动力学实验结果一致.1073 K下Fe-C-Mn/Si三元合金的珠光体-奥氏体相变由C扩散控制.更多还原

【Abstract】 The reverse transformation to austenite is an important part in the heat treatment process of steels.The final microstructures obtained by quenching,normalization or intercritical annealing(e.g.for dual phase steels) are strongly dependent upon the reverse transformation kinetics and austenitic structure.Therefore,it is of considerable technical interest to study and control the kinetics of this transformation.In order to clarify effects of substitutional alloying elements on the kinetics of reverse transformation from pearlite,an Fe-0.6C binary alloy and Fe-0.6C-1 or 2M(M=Mn, Si) ternary alloys were used in the present study(hereafter denoted as 0.6C,1Mn,2Mn and 1Si alloys, respectively).The initial pearlite structure of each alloy has nearly the same interlamellar spacing of 0.17μm.Thin sheets of 0.5 mm×5 mm×10 mm in size cut from the pearlitic specimen were firstly preheated in a salt bath at 923 K for 15 s,and then rapidly moved into another salt bath at 1073 K for reverse transformation for various periods,followed by water quenching.The variation of Vickers hardness and microstructure evolution with holding time at 1073 K were examined.Ferrite region without cementite remains inside or neighboring to austenite newly formed during reverse transformation in the 0.6C and 1Si pearlitic specimens.It is indicated that continuous dissolution of cementite in ferrite and continuous diffusion of C atoms through ferrite into the growth front of austenite occur.However, pearlitic ferrite and cementite almost simultaneously disappeared in the 1Mn and 2Mn specimens. Reverse transformation from pearlite in the 0.6C pearlitic specimen at 1073 K is finished after holding for about 5.5 s.The reversion kinetics is retarded by the addition of Si.On the other hand,the reversion kinetics is slightly accelerated by the addition of Mn.The difference of acceleration between the 1Mn and 2Mn pearlitic specimens is small.From the viewpoint of 1D austenite growth in a pearlite lamella,austenite can grow without long range diffusion of Mn and Si in the Mn- and Si-added pearlitic specimens,respectively.It is supposed that austenite growth is controlled by carbon diffusion in those specimens.The addition of Mn or Si affects carbon diffusion by affecting carbon concentrations at the austenite/ferrite and austenite/cementite interfaces,resulting in changes in reversion kinetics.更多还原