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Synthesis,Crystal Structure and Magnetic Property of a Novel Cu(Ⅱ)-Fluconazole-azide Complex

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【作者】 龚云； 秦建波； 郑凌玲； 曹荣；

【Author】 GONG Yuna,b② QIN Jian-Boa ZHENG Ling-Linga CAO Rongb a(Department of Chemistry,College of Chemistry and Chemical Engineering,Chongqing University,Chongqing 400044,China) b(State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China)

【机构】 Department of Chemistry,College of Chemistry and Chemical Engineering,Chongqing University； State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences；

【摘要】 The title compound formulated as Cu2(C13H11N6OF2)(N3)3CH3OH was synthesized and structurally characterized by elemental analysis,IR and single-crystal X-ray diffraction.In the structure of the complex,the deprotonated fluconazole and azide anion link two copper centers to construct a binuclear SBU and the azide anion exhibits a μ1,1-coordination mode.Each triazole group of fluconazole links two SBUs and the compound exhibits a chain-like architecture with strong antiferromagnetism.

【Abstract】 The title compound formulated as Cu2(C13H11N6OF2)(N3)3CH3OH was synthesized and structurally characterized by elemental analysis,IR and single-crystal X-ray diffraction.In the structure of the complex,the deprotonated fluconazole and azide anion link two copper centers to construct a binuclear SBU and the azide anion exhibits a μ1,1-coordination mode.Each triazole group of fluconazole links two SBUs and the compound exhibits a chain-like architecture with strong antiferromagnetism.

【关键词】 fluconazole； azide； crystal structure； synthesis； copper(II)； antiferromagnetism；
【Key words】 fluconazole； azide； crystal structure； synthesis； copper(II)； antiferromagnetism；
【基金】 Supported by the Chongqing University Postgraduate Science (No.200911A1B0010317);Innovation Fund and Innovative Talent Training Projects of the Third Stage of “211 Project”of Chongqing University(No.S-09103);the Natural Science Young Scholars Foundation of Chongqing University,Large-scale Instrument and Equipment Open Foundation of Chongqing University;Scientific Research Start-up Foundation of Chongqing University
  • 【文献出处】 结构化学 ,Chinese Journal of Structural Chemistry , 编辑部邮箱 ,2010年08期
  • 【分类号】O641.4
  • 【被引频次】3
  • 【下载频次】56
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