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高强度、高燃速丁羟推进剂配方工艺研究

Study on Formulation Process of Hydroxyl-terminated Polybutadiene Propellant With High Strength and High Burning Rate

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【作者】 苏昌银王世英韩晓娟樊瑛

【Author】 SU Changyin, WANG Shiying, HAN Xiaojuan, FAN ying (Xi’an Aerospace Chemical Propulsion Factory, Xi’an 710025, China)

【机构】 西安航天化学动力厂

【摘要】 对高不挥发物质量分数、高强度、高燃速丁羟推进剂进行了配方研究。采用了HTPB(端羟基聚丁二烯)、TDI(甲苯二异氰酸酯)黏合剂体系及STR增强剂的固化网络,选用SX-1助剂以改善工艺性能,通过优化AP级配、调节混合工艺程序等方法,使推进剂具有不挥发物质量分数>88%、密度>1.82g/cm3、20℃抗拉强度σm>3MPa、65℃抗拉强度σm≥2.3MPa,燃速>35mm/s的良好性能,并具有药浆初始黏度低,工艺流动流平性好的特点。

【Abstract】 The formulation of hydroxyl-terminated polybutadiene(HTPB) propellant with high mass fraction of non- volatile substance, high strength and high burning rate was investigated. The HTPB/TDI(toluene diisocyanate) binder system, STR reinforced curing network and assistant SX-1 were adopted to improve the processing property. The obtained propellant possesses excellent properties, such as mass fraction of non-volatile substance > 88%, density > 1.82 g/cm3, tensile strength σm> 3 MPa at 20℃, tensile strength σm≥ 2.3 MPa at 65℃, and burning rate > 35 mm/s by means of optimizing AP particle size distribution, modifying mixing process procedure and etc. Moreover, the propellant slurry exhibits low initial viscosity, and good process fluidity and self-leveling behavior.

  • 【文献出处】 化学推进剂与高分子材料 ,Chemical Propellants & Polymeric Materials , 编辑部邮箱 ,2010年04期
  • 【分类号】V512
  • 【被引频次】21
  • 【下载频次】432
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