【摘要】 "水上"有机反应的发展是水相绿色合成反应研究领域中的一个突破。体系的非均相性质是"水上"反应的基本特征。水不仅是重要的绿色反应介质,在大多数"水上"有机反应中都能观察到水对反应的速度和选择性有明显的提升作用。采用"水上"反应的条件,可以使反应的规模扩大,有利于产物的分离、纯化。本文以反应的类型分类综述了近年来有关"水上"有机反应研究的进展,以及在绿色有机合成中的应用。更多还原

【Abstract】 The development of "on water" organic reaction is a breakthrough in the field of aqueous organic reactions for green synthesis.An essential characteristic of "on water" reaction is heterogeneity of the reaction system.Water is not only used as a green reaction media,but also,in most "on water" reactions,plays a crucial role in observing large rate acceleration and selectivity enhancement.Under "on water" reaction conditions,the reaction can be scaled-up and the procedure is favorable to make a clear phase separation.The recent advancements of "on water" organic reaction and its applications in green organic synthesis are reviewed in terms of classification of organic reaction.更多还原