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等离子体改性对活性炭纤维低温选择性催化还原脱除NO的影响

Plasma modification of V-ACF for NO SCR at low temperatures

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【作者】 黄昕黄碧纯张春菊叶代启罗翠红

【Author】 HUANG Xin1,HUANG Bichun1,ZHANG Chunju1,YE Daiqi1,LUO Cuihong2(College of Environmental Science and Engineering,South China University of Technology,Guangzhou 510006;Guangzhou Environment Protection Investment CO.,Ltd.,Guangzhou 510660)

【机构】 华南理工大学环境科学与工程学院广州环保投资有限公司

【摘要】 采用介质阻挡放电(DBD)低温N2、O2等离子体技术对黏胶基活性炭纤维(V-ACF)进行表面改性,运用BET、SEM、NH3-TPD和FT-IR对催化剂进行表征,并对催化剂低温选择性催化还原(SCR)NO性能进行了研究。结果表明,N2、O2等离子体最佳改性时间分别为5 min与10 min,最佳反应温度为100℃,低温等离子体改性能明显提高ACF上NO转化率,且N2等离子体改性ACF催化效率高于O2等离子体改性ACF。

【Abstract】 Viscose-activated carbon fiber(V-ACF)modified by low-temperature N2 and O2 plasma with dielectric barrier discharge(DBD)was studied for low-temperature selective catalytic reduction(SCR) of NO.Structure of the plasma modified V-ACF was characterized by BET,SEM,NH3-TPD and FT-IR.Experimental results showed that the optimal surface modification time was 5 and 10 minutes for N2 and O2 plasma,respectively.The optimal reaction temperature was 100℃.Surface modification of V-ACF by low-temperature plasma technology could greatly improve the NO removal rate.V-ACF modified by N2 plasma showed higher NO removal rate than that modified by O2 plasma.

【基金】 国家自然科学基金(20977034);广州重大科技专项计划(X2DLB2080501);工业聚集区污染控制与生态修复教育部重点实验室项目
  • 【文献出处】 化工进展 ,Chemical Industry and Engineering Progress , 编辑部邮箱 ,2010年11期
  • 【分类号】X701.7
  • 【被引频次】13
  • 【下载频次】456
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