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Mn-Ce催化剂催化湿式氧化降解正丁酸过程的模拟研究

Simulated study on degradation progress of butyric acid by catalytic wet air oxidation over Mn-Ce catalyst

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【作者】 郑爽胡艳陈宇刘建林李鱼

【Author】 ZHENG Shuang2,HU Yan1,CHEN Yu2,LIU Jian-lin1,LI Yu1,2(1.Sino-Canada Research Academy of Energy and Environmental Studies,North China Electric Power University,Beijing 102206,China;2.College of Environment and Resources,Jilin University,Changchun 130012,China)

【机构】 吉林大学环境与资源学院华北电力大学能源与环境研究院

【摘要】 对垃圾渗滤液中大量存在的有机酸——正丁酸进行了Mn-Ce复合氧化物催化剂催化湿式氧化降解的研究,并采用统计回归分析法建立了Mn-Ce催化剂催化湿式氧化降解正丁酸升温和恒温过程的降解模型。回归方程的残差分析结果表明,Mn-Ce催化剂催化湿式氧化降解正丁酸升温和恒温过程的降解模型计算值与实验值吻合良好;此外,回归方程的决定系数(R2)以及Nash-Suttcliffe模拟效率系数(NSC)均达到0.80以上,表明模型预测准确度较高。

【Abstract】 In this paper,the n-butyric acid that abounds in landfill leachate was used to be degraded over Mn/Ce catalyst by catalytic wet air oxidation,and the models that the heating and constant temperature reaction process of n-butyric acid degradation were established by statistical regression analysis method.The residual results of the regression equations show that the values calculated from the two models are well agreed with the experimental data.The coefficient of determination(R2) and Nash-Suttcliffe coefficient(NSC) of the prediction models for heating and reaction processes are both more than 0.80,indicating that the two models predict well.

【基金】 吉林省环境保护资助项目(吉环科字第03-07)
  • 【文献出处】 华北电力大学学报(自然科学版) ,Journal of North China Electric Power University(Natural Science Edition) , 编辑部邮箱 ,2010年03期
  • 【分类号】X703
  • 【被引频次】1
  • 【下载频次】151
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