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硝化过程亚硝态氮氧化阶段的N2O产生情况

Production of Nitrous Oxide from Nitrite Nitrogen Oxidation during Nitrification of Domestic Sewage

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【作者】 张静蓉王淑莹尚会来彭永臻

【Author】 ZHANG Jing-rong,WANG Shu-ying,SHANG Hui-lai,PENG Yong-zhen(Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering,Beijing University of Technology,Beijing 100124,China)

【机构】 北京工业大学水质科学与水环境恢复工程北京市重点实验室

【摘要】 为考察生活污水硝化过程的亚硝态氮氧化阶段是否有N2O产生,利用经生活污水长期驯化后的污泥和SBR反应器,在pH值为8、曝气量为60L/h的条件下,研究了不同NO2-N浓度下N2O的产生情况。试验发现,除了氨氧化阶段,NO2-N氧化阶段也是N2O的重要产生源。调节NO2-N浓度分别为81.45、65.29、40.18和16.82mg/L,结果发现随着NO2-N浓度的降低,N2O的产生量和转化率也有所降低,但当NO2-N浓度降低至1.64mg/L时,N2O的产生量和转化率却有所升高。此外,还考察了NO2-N浓度为30mg/L左右时,不同pH下N2O的产生情况。结果表明,随着pH的升高则N2O的产量逐渐减少。综合考虑运行成本和减少N2O生成量的效果,应控制pH值在7以上。

【Abstract】 Long-term acclimated sludge and SBR were used to investigate the production of nitrous oxide(N2O)from nitrite nitrogen oxidation during nitrification of domestic sewage under the conditions of pH 8,aeration rate 60 L/h and different nitrite nitrogen concentrations.Besides ammonium oxidation,nitrite nitrogen oxidation process is an important source of N2O.When nitrite nitrogen concentrations are regulated at 81.45 mg/L,65.29 mg/L,40.18 mg/L and 16.82 mg/L respectively,the production and conversion rate of N2O are gradually reduced.However,when nitrite nitrogen concentration is decreased to 1.64 mg/L,the production and conversion rate of N2O are increased.With the increase of pH,the production of N2O is gradually reduced when nitrite nitrogen concentration is 30 mg/L.Taking the operation cost and reduction of N2O emission into account,pH should be controlled at more than 7.

【关键词】 污水处理亚硝态氮N2OpH
【Key words】 sewage treatmentnitrite nitrogennitrous oxidepH
【基金】 国家“十一五”科技支撑计划重点项目(2006BAC19B03);北京市教委科技创新平台项目(PXM2008_014204_050843);北京工业大学研究生科技基金资助项目(YKJ-2009-2909)
  • 【文献出处】 中国给水排水 ,China Water & Wastewater , 编辑部邮箱 ,2010年03期
  • 【分类号】X703
  • 【被引频次】27
  • 【下载频次】461
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