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5,5′-二甲基-2,2′-二茚满-1,1′,3,3′-四酮的合成及结构表征

Synthesis and Characterization of 5,5′-Dimethyl-2,2′-bisindan-1,1′,3,3′-tetrone

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【作者】 李平孟继本

【Author】 LI Ping1,MENG Ji-Ben2(1.School of Chemistry and Chemical Engineering,Tianjin University of Technology,Tianjin 300384,China; 2.Department of Chemistry,Nankai University,Tianjin 300071,China)

【机构】 天津理工大学化学化工学院南开大学化学系

【Abstract】 Based on the synthesis of 2,2′-bisindan-1,1′,3,3′-tetrone(1),5,5′-dimethyl-2,2′-bisindan-1,1′,3,3′-tetrone(2) was obtained.This paper described the synthetic process and confirmed the characteristic of compound 2 by elemental analysis,1H NMR,FTIR and MS,then discussed a possible existing form.Compound 2 maily existed as en-ol form and had H-bonds in the molecule.At the same time,the ESR value of compound 2 was given as g=2.0042,could form stable radical.

【基金】 国家自然科学基金(批准号:20372039)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2010年06期
  • 【分类号】TQ244.2
  • 【下载频次】110
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