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激光诱导荧光光谱法检测高纯激光晶体中的痕量稀土杂质

Determination of trace rare earth impurities in high purity laser crystals using laser-induced fluorescence

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【作者】 臧竞存邹玉林

【Author】 Zang Jingcun, Zou Yulin (College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124)

【机构】 北京工业大学材料科学与工程学院

【摘要】 以功率为40mW、波长为488nm的氩离子激光器作为激发光源,采用S2000光谱仪接收荧光。在高纯激光晶体Er:YAG中检测出痕量Nd3+离子4F3/2→4I9/2跃迁的946nm特征荧光峰和Yb3+离子2F5/2→2F7/2跃迁的1030nm特征荧光峰,钕和镱的痕量浓度低于2×10-6。同样方法在Pr:GdVO4单晶中检测到痕量Nd3+和Yb3+的荧光发射,特征峰分别在912nm和1031nm处,钕和镱的痕量浓度低于0.7×10-6。

【Abstract】 Using Ar3+ laser (with power of 40mV and emitting wavelength of 488nm) as excitation source, trace impurities of Nd3+ and Yb3+ ions (concentrations lower than 2×10-6) in high purity laser crystal Er ︰YAG were detected using laser-induced fluorescence. The characteristic fluorescence peak at 946nm is corresponding to 4F3/2→4I9/4 transition of Nd3+, and the peak at 1030nm is corresponding to 2F5/2→2F7/2 transition of Yb3+. Trace Nd3+ and Yb3+ (concentrations lower than 0.7×10-6) in Pr ︰GdVO4 crystal were detected by the same method also, with the emission peak at 912nm corresponding to Nd3+, and at 1031nm corresponding to Yb3+.

【关键词】 荧光光谱Er:YAGPr:GdVO4
  • 【文献出处】 分析仪器 ,Analytical Instrumentation , 编辑部邮箱 ,2010年03期
  • 【分类号】TG115.33
  • 【被引频次】2
  • 【下载频次】140
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