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BaAl12O19:Mn2+和YPO4:Tb3+共混对等离子绿色发光体发光性能的改善

Improvement of Luminescence Performance on Green-emitting PDP Phosphor by Blending BaAl12O19:Mn2+ and YPO4:Tb3+

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【作者】 任新光狄卫华

【Author】 REN Xin-guang,DI Wei-hua(Key Laboratory of Excited State Processes,Changchun Institute of Optics,Fine Mechanics and Physics,Chinese Academy of Sciences,Changchun 130033,China)

【机构】 中国科学院长春光学精密机械与物理研究所激发态物理重点实验室

【摘要】 等离子体平板显示用绿色发光粉主要有硅酸盐(Zn2S iO4∶Mn2+)、铝酸盐(BaA l12O19∶Mn2+)、磷酸盐(YPO4∶Tb3+)和硼酸盐(YBO3∶Tb3+)4种体系。前两者具有量子效率高、色纯度好等优点,然而抗真空紫外辐照能力差,发光衰减时间长;Tb3+激活的磷酸盐和硼酸盐体系具有适宜的发光寿命,抗真空紫外辐射能力强,然而Tb3+的发射光是黄绿色,色纯度不够好,且发光亮度相对较弱。按一定的混合比率使BaA l12O19∶Mn2+和YPO4∶Tb3+均匀混合,组合这两种体系绿色发光粉各自的优点,优化了等离子体平板显示用绿色发光粉的整体性能。

【Abstract】 The research on Plasma display panel(PDP) phosphors has gained much attention.The green PDP phosphor is an important component due to its highest brightness in three-color-based phosphors.Existing and developing green-emitting phosphors include Mn-activated silicates and aluminates,and Tb-activated phosphates and borates systems.Mn-activated silicates and aluminates have high quantum efficiency and excellent color coordinate,but low stability to vacuum ultraviolet(VUV) radiation and long decay time.Tb-activated phosphates and borates have suitable decay time and high stability to VUV radiation,but low brightness and color purity.This work investigates the luminescent performance of single BaAl12O19∶Mn2+,YPO4∶Tb3+,and especially their blends.The result indicates that the blends of BaAl12O19∶Mn2+ and YPO4∶Tb3+ can effectively combine their respective advantages to improve the overall luminescent performance of green-emitting phosphors for PDP application.

【关键词】 稀土绿色发光粉PDP
【Key words】 rare earthgreen-emitting phosphorsPDP
【基金】 国家自然科学基金(50502031);吉林省科技厅自然科学基金(20060522)资助项目
  • 【文献出处】 发光学报 ,Chinese Journal of Luminescence , 编辑部邮箱 ,2010年06期
  • 【分类号】O482.31
  • 【被引频次】4
  • 【下载频次】125
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