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添加Mg、Y氧化物对Fe-Mo/Si3N4金属陶瓷微观组织与性能的影响

Effect of Mg-Y Oxides on the Microstructure and Properties of Fe-Mo/Si3N4 Cermet

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【作者】 银锐明范景莲刘勋张曙光

【Author】 YIN Ruiming~(1,2) FAN Jinglian~(1**) LIU Xun~1 ZHANG Shuguang~1 1.State Key Laboratory of Powder Metallurgy,Central South University,Changsha 410083 2.College of Packaging and Material Engineering,Hunan University of Technology,Zhuzhou 412008

【机构】 中南大学粉末冶金国家重点实验室湖南工业大学包装与材料工程学院

【摘要】 提出在Fe-Mo/Si3N4金属陶瓷中添加Mg、Y氧化物,在常压烧结条件下实现金属复合、晶须技术双重强韧化陶瓷,并研究了Mg、Y氧化物对Fe-Mo/Si3N4金属陶瓷的微观组织与性能的影响.结果表明:添加Mg、Y氧化物的Fe-Mo/Si3N4金属陶瓷,存在与Si3N4润湿性极好的金属Fe与MoSi2相,颗粒状α-Si3N4转变成晶须条状β-Si3N4,烧结体致密且晶粒得到明显细化,各项性能得到大幅提升,实现了金属复合、晶须技术双重强韧化Si3N4陶瓷。

【Abstract】 The paper proposes a dual-toughening method of ceramic,including metal composite and crystal whiskers strengthening,through adding Mg-Y oxides into Fe-Mo/Si3N4 cermet and subsequently consolidated by normal pressure sintering.The effects of Mg-Y oxides on the microstructure and properties of the Fe-Mo/Si3N4 cermet have been investigated.The results show that Fe and MoSi2 phases with good wettability on Si3N4 are formed in the Fe-Mo/Si3N4 cermet with Mg-Y oxides addition.Additionally, granularα-Si3N4 converts into whisker-shapedβ-Si3N4,simultaneously with obvious densification,grain refinement and significantly improved properties,indicating that the dual-toughening method of the metal composite and the crystal whiskers have been realized.

【基金】 国家自然科学青年基金50804016;国家杰出青年科学基金50925416资助项目~~
  • 【文献出处】 材料研究学报 ,Chinese Journal of Materials Research , 编辑部邮箱 ,2010年03期
  • 【分类号】TG148
  • 【被引频次】6
  • 【下载频次】167
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