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镀锌层表面KH-560硅烷膜耐蚀性能研究

Study of the Corrosion Resistance of KH-560 Silane Film on Hot-dip Galvanzied Steels

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【作者】 韩利华马庆国冯晓健康举

【Author】 HAN Li-hua,MA Qing-guo,FENG Xiao-jian,KANG Ju(School of Chemical Engineering and Biotechnology,Hebei Polytechnic University,Tangshan 063009,Hebei,China)

【机构】 河北理工大学化工与生物技术学院

【摘要】 利用正交实验研究了硅烷偶联剂在镀锌板上的钝化工艺,采用KH-560对热镀锌板进行钝化处理。比较钝化膜与空白试样在5%NaCl溶液中的极化曲线、电化学交流阻抗谱,并通过盐水浸泡实验进一步验证了硅烷膜的耐蚀性能。结果表明:经硅烷钝化处理后的镀锌板,其腐蚀电流密度下降,极化电阻升高,硅烷膜抑制了镀锌板的腐蚀过程,其耐蚀性能优于空白试样,接近铬酸盐钝化膜的耐蚀性。

【Abstract】 Orthogonal experiment was used to study the passivation process on galvanized steel with silane.A KH-560 silane passivating treatment process was studied on galvanized steel.The electrochemical behavior of KH-560 silane film on galvanized steel in 5% NaCl solution was evaluated by polarization curves and electrochemical impendence spectroscopy.And more by the NaCl immersion test validate the corrosion resistance of KH-560 silane film.Results showed that the corrosion current density decreases and the polarization resistance increases after KH-560 passivation.KH-560 silane film inhibits the corrosion rate of the galvanized steel.After KH-560 passivating treatment,the corrosion resistance of the conversion coating was better than that of without passive films,and almost as well as chromate coatings.

【关键词】 硅烷膜镀锌层铬酸盐耐蚀性能
【Key words】 silane filmzinc coatingchromatecorrosion resistance
  • 【文献出处】 材料工程 ,Journal of Materials Engineering , 编辑部邮箱 ,2010年06期
  • 【分类号】TG174.44
  • 【被引频次】33
  • 【下载频次】480
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