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热硫化条件下温度对黄铁矿结晶生长的影响

Temperature Influence on Pyrite Crystallization Growth Under Conditions of Thermal-Sulfurization

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【作者】 寇大明黄菲杨大勇李光禄王岳松谭伟郭耀宇

【Author】 KOU Da-ming,HUANG Fei,YANG Da-yong,LI Guang-lu,WANG Yue-song,TAN Wei,GUO Yao-yu College of Resources and Civil Engineering,Northeast University,Shenyang 110004,China

【机构】 东北大学资源与土木工程学院

【摘要】 模拟天然黄铁矿形成条件和基本过程,利用真空管式炉实验设备,通过热硫化法在250~410℃反应,实验考察不同温度条件下黄铁矿的结晶生长情况。运用扫描电镜、X射线粉晶衍射分析等手段,对实验产物形貌、物相结构特点等进行测试分析。结果表明:250~410℃时均可形成黄铁矿,但250~280℃时黄铁矿结晶程度较差;310~340℃时,可生长出部分晶面;360℃时黄铁矿生长成较为完好的晶体;380℃时黄铁矿结晶成立方体、八面体等自形晶;410℃时可形成结晶好、成分单一的黄铁矿。

【Abstract】 Natural conditions and formation process for pyrite were simulated.A laboratory vacuum tube furnace heater was used through the thermal curing process between 250℃ and 410℃.Responses were captured from the experimental study at different temperatures under the conditions of pyrite crystallization growth.Using the methods such as scanning electron microscope and X-ray diffraction analysis,the authors analyzed the pyrite in crystal form and structure.The results show that it is formed between 250℃ and 410℃,but it is low in degree of crystallization between 250℃ and 280℃.The partial crystal faces begin to grow between 310℃ and 340℃,and better crystal planes occur at 360℃.It has euhedral crystals that appear as cubes and octahedrons at 380℃.When it is 410℃,the pyrite crystallizes completely with a single composition.

【基金】 国家自然科学基金项目(40872045);内生金属矿床成矿机制研究国家重点实验室(南京大学)开放基金项目(12-06-03);地质过程与矿产资源国家重点实验室(中国地质大学)开放课题(GPMR200906)
  • 【文献出处】 吉林大学学报(地球科学版) ,Journal of Jilin University(Earth Science Edition) , 编辑部邮箱 ,2010年01期
  • 【分类号】P578.24
  • 【被引频次】14
  • 【下载频次】517
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