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钎焊立方氮化硼BCu80Ni5SnTi活性钎料的组织与性能

Microstructure and properties of BCu80Ni5SnTi active filler metal for brazing cubic boron nitride

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【作者】 王毅殷世强卢广林李世权邱小明

【Author】 WANG Yi1,2,YIN Shi-qiang1,LU Guang-lin3,LI Shi-quan1,QIU Xiao-ming1(1.School of Materials Science and Engineering,Jilin University,Changchun 130025,China;2.School of Mechatronies Engineering,Changchun Institute of Technology,Changchun 130012,China;3.The Key Laboratory for Terrain-machine Bionics Engineering,Ministry of Education,Jilin University,Changchun 130025,China)

【机构】 吉林大学材料科学与工程学院长春工程学院机电学院吉林大学地面机械仿生技术教育部重点实验室

【摘要】 研制一种适合钎焊立方氮化硼与45钢异质材料的新型高温BCu80Ni5SnTi活性钎料,采用SEM、EDS及XRD对BCu80Ni5SnTi系活性钎料的微观组织及钎焊接头力学性能进行研究。结果表明:适合钎焊c-BN的活性钎料成分为Cu78~81Ni5~6Sn3~5.5Ti10~12(质量分数,%),固相线温度为858.4℃,液相线温度为874.8℃;钎料组织由α-Cu固溶体、Ni固溶体、Cu-Sn共晶及少量Cu4Ti3、Cu3Ti2、Cu3Sn、CuSn和Ni17Sn3等化合物组成;该钎料对c-BN的润湿性较好,润湿角为28°~30°,钎焊c-BN与45钢的接头强度为210~230MPa;新型钎料钎焊冶金特性较好,钎焊接头界面实现冶金结合。

【Abstract】 A new-type BCu80Ni5SnTi filler metal suitable for brazing cubic boron nitride(c-BN) and 45 steel was prepared.The microstructures of BCu80Ni5SnTi active filler metal and mechanical properties of the joints of c-BN and 45 steel brazed with BCu80Ni5SnTi filler metal were analyzed by SEM,EDS and XRD.The results show that the solidus and liquidus temperatures of the novel BCu78-81Ni5-6Sn3-5.5Ti10-12(mass fraction,%) active filler metal are 858.4 and 874.8 ℃,respectively.The microstructure of the filler metal mainly consists of α-Cu solid solution,Ni solid solution,Cu-Sn eutectic phase as well as a little Cu4Ti3,Cu3Ti2,Cu3Sn,CuSn and Ni17Sn3 compounds.The wettability of the filler metal on c-BN is good and the contact angle is about 28°-30°.The shear strength of the brazed joint between c-BN and 45 steel using this active filler metal reaches 210-230 MPa.The new-type BCu78-81Ni5-6Sn3-5.5Ti10-12(mass fraction,%) active filler metal possesses better brazing metallurgy characteristics.Chemical metallurgic joining forms in the interface between c-BN grits and BCu80Ni5SnTi active filler metal.

【基金】 国家自然科学基金重点资助项目(50635030);吉林省科技发展计划资助项目(20070309);长春市科技计划资助项目(06GJ22)
  • 【文献出处】 中国有色金属学报 ,The Chinese Journal of Nonferrous Metals , 编辑部邮箱 ,2009年12期
  • 【分类号】TG425
  • 【被引频次】12
  • 【下载频次】247
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