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Interfacial characteristics of high frequency induction brazed Cu and pre-metalized graphite joints

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【作者】 谢凤春张丽霞何鹏冯吉才

【Author】 XIE Feng-chun1,ZHANG Li-xia 1,HE Peng2,FENG Ji-cai1 (1. National Key Laboratory of Advanced Welding Production Technology,Harbin Institute of Technology,Harbin 150001,China; 2. National Key Laboratory of Precision Hot Processing of Metals,Harbin Institute of Technology,Harbin 150001,China)

【机构】 National Key Laboratory of Advanced Welding Production Technology,Harbin Institute of TechnologyNational Key Laboratory of Precision Hot Processing of Metals,Harbin Institute of Technology

【摘要】 Oxygen-free copper and pre-metalized graphite were brazed using CuNiSnP braze alloy by high frequency induction heating method. Interfacial microstructures and reaction phases were analyzed by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The strength and resistance of the joints were tested. It is found that when the brazing parameters are optimized,the structures of the joints are graphite/(Cu,Ni)/Ni(s.s)+NixPy/Cu3P+Cu(s.s) (including Sn)+eutectic structures (Cu3P+Ni3P+Cu(s.s)/Cu (s.s)/Cu). When the temperature increases to 750 ℃ or the holding time prolongs to 300 s,the eutectic structures disappear and the amount of Cu3P increases. The maximum shear strength of the joints is 5.2 MPa,which fracture at the interface of graphite and metallization. The resistance of the joints is no more than 5 m-.

【Abstract】 Oxygen-free copper and pre-metalized graphite were brazed using CuNiSnP braze alloy by high frequency induction heating method. Interfacial microstructures and reaction phases were analyzed by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The strength and resistance of the joints were tested. It is found that when the brazing parameters are optimized,the structures of the joints are graphite/(Cu,Ni)/Ni(s.s)+NixPy/Cu3P+Cu(s.s) (including Sn)+eutectic structures (Cu3P+Ni3P+Cu(s.s)/Cu (s.s)/Cu). When the temperature increases to 750 ℃ or the holding time prolongs to 300 s,the eutectic structures disappear and the amount of Cu3P increases. The maximum shear strength of the joints is 5.2 MPa,which fracture at the interface of graphite and metallization. The resistance of the joints is no more than 5 m-.

【基金】 Project(50705022) supported by the National Natural Science Foundation of China;Project supported by the Program for New Century Excellent Talents in University
  • 【文献出处】 Journal of Central South University of Technology ,中南大学学报(英文版) , 编辑部邮箱 ,2009年06期
  • 【分类号】TG454
  • 【被引频次】3
  • 【下载频次】76
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