【摘要】 采用表面活性剂为模板,通过分子自组装法合成了孔状纳米级锂离子正极材料LiFePO₄。并结合XRD、SEM、N₂吸附/脱附和充放电测试等手段,对合成材料的结构、形貌、孔的分布和电化学性能进行了分析。实验结果表明:表面活性剂为模板,通过高温烧结脱去可以形成纳米孔状的LiFePO₄正极材料,在以0.1mA的电流下放电,首次放电比容量有125.5mA·h/g,循环20次后其比容量仍有120mA·h/g,保持率达95.6%。更多还原

【Abstract】 The nanostructured IiFePO₄ positive electrode of Li-ion secondary batteries were synthesized by template assisted molecular self-assembly.Then the template was easily removed by high temperature sintering.The microstructures, morphology,and electrical properties of the electrode were characterized with X-ray diffraction（XRD）,scanning electron microscopy（SEM）,nitrogen adsorption/desorption and charge-discharge test.The results show that the surfactant template is responsible for high quality,nano-structured,self-assembled LiFePO₄ electrode.We found that the initial specific discharge capacity was 125.5mA·h/g;at a current of 0.1mA,the specific discharge capacity was found to be 120mA ?h/g,after 20 cycles and a rate of capacity fade was 4.4%.更多还原