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Electrical,dielectric and surface wetting properties of multi-walled carbon nanotubes/nylon-6 nanocomposites

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【作者】 龙云泽李蒙蒙隋万美孔庆山张磊

【Author】 Long Yun-Ze a),Li Meng-Meng a),Sui Wan-Mei a),Kong Qing-Shan b),and Zhang Lei a) a)College of Physics Science,Qingdao University,Qingdao 266071,China b)Laboratory of Fibre Materials and Modern Textile,the Growing Base for State Key Laboratory,Qingdao University,Qingdao 266071,China

【机构】 College of Physics Science,Qingdao UniversityLaboratory of Fibre Materials and Modern Textile,the Growing Base for State Key Laboratory,Qingdao University

【摘要】 This paper reports that the multi-walled carbon nanotubes(MWCNT)/nylon-6(PA6) nanocomposites with different MWCNT loadings have been prepared by a simple melt-compounding method.The electrical,dielectric,and surface wetting properties of the CNT/PA6 composites have been studied.The temperature dependence of the con-ductivity of the CNT/PA6 composite with 10.0 wt% CNT loading(σRT-10-4 S/cm) are measured,and afterwards a charge-energy-limited tunnelling model(ln σ(T)-T-1/2) is found.With increasing CNT weight percentage from 0.0 to 10.0 wt%,the dielectric constant of the CNT/PA6 composites enhances and the dielectric loss tangent increases two orders of magnitude.In addition,water contact angles of the CNT/PA6 composites increase and the composites with CNT loading larger than 2.0 wt% even become hydrophobic.The obtained results indicate that the electrical and surface properties of the composites have been significantly enhanced by the embedded carbon nanotubes.

【Abstract】 This paper reports that the multi-walled carbon nanotubes(MWCNT)/nylon-6(PA6) nanocomposites with different MWCNT loadings have been prepared by a simple melt-compounding method.The electrical,dielectric,and surface wetting properties of the CNT/PA6 composites have been studied.The temperature dependence of the con-ductivity of the CNT/PA6 composite with 10.0 wt% CNT loading(σRT-10-4 S/cm) are measured,and afterwards a charge-energy-limited tunnelling model(ln σ(T)-T-1/2) is found.With increasing CNT weight percentage from 0.0 to 10.0 wt%,the dielectric constant of the CNT/PA6 composites enhances and the dielectric loss tangent increases two orders of magnitude.In addition,water contact angles of the CNT/PA6 composites increase and the composites with CNT loading larger than 2.0 wt% even become hydrophobic.The obtained results indicate that the electrical and surface properties of the composites have been significantly enhanced by the embedded carbon nanotubes.

【基金】 supported by the National Natural Science Foundation of China (Grant No 10604038);the Program for New Century Excellent Talents in University of China (Grant No NCET-07-0472)
  • 【文献出处】 Chinese Physics B ,中国物理B , 编辑部邮箱 ,2009年03期
  • 【分类号】O613.71;TB383.1
  • 【被引频次】3
  • 【下载频次】111
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