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酸性土壤中模拟硝酸型酸雨作用下X70钢的腐蚀行为

CORROSION BEHAVIOUR OF X70 STEEL IN SIMULATED NITRIC ACID RAIN IN ACID SOIL

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【作者】 许进王海峰王欣孙成王福会于长坤

【Author】 XU Jin~1,WANG Haifeng~2,WANG Xin~3,SUN Cheng~1,WANG Fuhui~1,YU Changkun~1 (1.State Key Laboratory for Corrosion and Protection,Institute of Metal Research,Chinese Academy of Sciences,Shenyang,110016;2.Qinghai Salt Lake Potash co.Ltd.,Geermu,816000; 3.Shenyang Broadcasting and Television University,Institute of Science and Technology,Biochemistry Department,Shenyang,110003)

【机构】 中国科学院金属研究所金属腐蚀与防护国家重点实验室青海盐湖钾肥股份有限公司沈阳广播电视大学理工学院生化系

【摘要】 采用极化曲线、电化学阻抗谱、X射线衍射分析(XRD)及扫描电子显微镜(SEM)等方法,研究酸性土壤中不同pH值模拟硝酸型酸雨对X70钢腐蚀行为的影响。结果表明,酸性土壤中模拟硝酸型酸雨对埋地X70钢的腐蚀起加速作用;XRD结果表明X70钢表面的腐蚀产物主要由Fe2O3和SiO2组成;SEM分析表明随着淋溶液pH值的升高试样表面粗糙度逐级降低,气孔数量逐渐减少。

【Abstract】 The effects of simulated nitric acid rain in different pH value on X70 steel in acidic soil were studied by means of polarization curves、electrochemical impedance spectroscopy(eis)、x-ray diffraction(xrd)、scanning electron microscopy(sem) etc.The results revealed that simulated acid rain could heavily increase the corrosion rate of X70 buried;The results of X-ray showed that corrosion products mainly consist of Fe2O3,SiO2;The results of SEM showed that with the increasing of pH value surface roughness was falling and quantities of microspores decreasing.

【关键词】 酸性土壤模拟硝酸型酸雨X70钢
【Key words】 acid soilsimulated nitric acid rainX70 steel
【基金】 国家自然科学基金面上项目(50671112);科技部国家科技基础平台项目(2005DKA10400-CT-2-02)资助
  • 【文献出处】 中国腐蚀与防护学报 ,Journal of Chinese Society for Corrosion and Protection , 编辑部邮箱 ,2009年05期
  • 【分类号】TG174.3
  • 【被引频次】6
  • 【下载频次】182
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