【摘要】 以O2气为氧源,在无溶剂无引发剂条件下,研究了非催化剂体系中环辛烯环氧化反应,并考察了反应温度、时间、压力、自由基引发剂以及自由基阻聚剂对环辛烯环氧化反应的影响。实验结果表明,在无催化剂条件下,当反应初压0.60MPa,反应时间2.0h时,在140℃的较高温度下,以分子氧为氧源,环辛烯的转化率为44.5%,环氧环辛烷的选择性可达到64.4%。更多还原

【Abstract】 The uncatalyzed epoxidation of cyclooctene with molecular oxygen as oxidant under solvent-free and no-inducement conditions has been studied.The effects of reaction conditions sush as temperature,time and pressure on the epoxidation of cyclooctene were investigated.The 44.5% of cyclooctene conversion and 64.4% of cyclooctane epoxide selectivity were obtained when the reaction was carried out at 140 ℃ and initial O2 pressure 0.60 MPa for 2.0 h.更多还原