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磷酸中铜阳极电溶解过程的复杂电流振荡分析

Analysis on Complex Current Oscillation of Copper Anodic Dissolution in Phosphoric Acid

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【作者】 吴世彪徐玲

【Author】 WU Shi-biao,XU Ling (School of Material & Chemical Engineering,Anhui Institute of Architecture & Industry,Hefei 230022,China)

【机构】 安徽建筑工业学院材料与化学工程学院

【摘要】 通过用计算机控制的PCI-1710HG数据采集卡记录和用Matlab分析程序处理电流时间序列,使用恒电位方法研究磷酸中铜阳极电溶解过程的复杂电流振荡。结果表明,在电溶解过程中存在确定性的电流混沌。在利用时间序列重构三维相空间吸引子时,提出了一种确定最优延迟时间的可操作的定量方法。

【Abstract】 The complex current oscillation of the copper anodic dissolution in phosphoric acid is investigated with potentiostatical method by using the electrochemical apparatus connected with a Pentium computer with PCI-1710HG card and Matlab nonlinear analysis program for record and disposal of the complex current time-series. The results show that the determinative current chaos exist during the electrodissolution.An operational quantitative method is put forward and used to determine the optimal delay time when 3-dimension phase space attractor of the timeseries is reconstructed.

  • 【分类号】O646.5
  • 【被引频次】4
  • 【下载频次】83
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