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铌酸盐无铅压电薄膜的脉冲激光沉积制备研究

Study on the Preparation of Niobate Lead-free Piezoelectric Ceramic Films by Pulse Laser Deposition

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【作者】 陆雷肖定全赁敦敏张永彬朱建国

【Author】 LU Lei1,2,XIAO Ding-quan1,LIN Dun-min1,3,ZHANG Yong-bin2,ZHU Jian-guo1(1.School of Material Science and Engineering,Sichuan University,Chengdu 610064,China; 2.China Academy of Engineer Physics,Mianyang 621900,China;3.Dept.of Applied Physics,the Hongkong Polytechnic University,Kowloon,China)

【机构】 四川大学材料科学与工程学院中国工程物理研究院香港理工大学应用物理系

【摘要】 采用脉冲激光沉积(PLD)在Pt/Ti/SiO2/Si基片上制备了新型Li0.04(Na0.5K0.5)0.96(Nb0.775Ta0.225)O3无铅压电陶瓷薄膜,分别利用X-射线衍射仪(XRD)和扫描电镜(SEM)研究了该薄膜的晶体结构及表面形貌,分析研究了制备技术和工艺对薄膜晶体结构及表面形貌的影响。研究结果表明:薄膜的热处理温度和氧气压力对所生长的薄膜影响较大;制备Li0.04(Na0.5K0.5)0.96(Nb0.775Ta0.225)O3薄膜的最佳退火温度和氧气压力分别为650℃和30 Pa;利用脉冲激光沉积的Li0.04(Na0.5K0.5)0.96(Nb0.775Ta0.225)O3无铅压电陶瓷薄膜具有精细的表面结构。

【Abstract】 A new type of lead-free piezoelectric ceramic films,Li0.04(Na0.5K0.5)0.96(Nb0.775Ta0.225)O3,has been prepared by pulsed laser deposition technique on Pt/Ti/SiO2/Si substrates.The crystal structure and surface morphology of the films have been studied with X-ray diffraction(XRD) and scanning electron microscopy(SEM).The effect of fabrication technologies on the crystal structure and surface morphology of the films has been investigated.The results showed that the properties of the Li0.04(Na0.5K0.5)0.96(Nb0.775Ta0.225)O3 films deposited are strongly dependent on the substrate temperature and the oxygen pressure of the camber.The annealing temperature of 650 ℃ and the camber oxygen pressure of 30 Pa are found to be optimized parameters for the growth of better textured film.The deposited Li0.04(Na0.5K0.5)0.96(Nb0.775Ta0.225)O3 films by PLD in present work are fine,uniform and dense.

【基金】 国家自然科学基金资助项目(50410179,50572066和50772068)
  • 【文献出处】 压电与声光 ,Piezoelectrics & Acoustooptics , 编辑部邮箱 ,2009年01期
  • 【分类号】TB383.2
  • 【被引频次】2
  • 【下载频次】270
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