【摘要】 通过Zn(Py)2(NCS)2和三(3,5-二甲基吡唑)甲烷(tmpzm)的反应,合成了一种未见报道的锌配合物.配合物结构通过单晶X射线衍射法测定,其晶体属正交晶系,空间点群为Pnma,a=2.1564(3),b=2.2050(3),c=1.06135(15)nm,V=5.0467(12)nm3,Z=2,Mr=959.92,Dc=1.302 g/cm3,μ(Mo Kα)=1.160 mm-1,F(000)=2048,R=0.0525,Rw=0.1543.更多还原

【Abstract】 A new zinc complex has been synthesized by the reaction of dipyridine zincthiocyanate and tris-(3,5-dimethylpyrazolyl)methane.Its structure was determined by single-crystal X-ray diffraction,crystallizing in orthorhombic space group Pnma with a=2.156 4(3),b=2.205 0(3),c=1.061 35(15) nm,V=5.046 7(12) nm3,Z=2,Mr=959.92,Dc=1.302 g/cm3,μ(Mo Kα)=1.160 mm-1,F(000)=2 048,R=0.052 5,Rw=0.154 3.更多还原