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木浆乙酰化工艺研究

Study on technology of acetylation of wood pulp

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【作者】 王海云李芬芬储富祥蔡智慧王春鹏

【Author】 WANG Hai-yun1,2,LI Fen-fen2,CHU Fu-xiang1,CAI Zhi-hui2,WANG Chun-peng1(1.Institute of Chemical Industry of Forest Products,CAF,Nanjing 210042,China;2.College of Chemical Engineering,Nanjing Forestry University,Nanjing 210037,China)

【机构】 中国林业科学研究院林产化学工业研究所南京林业大学化学工程学院

【摘要】 对木浆进行乙酰化,研究不同活化和酯化工艺对木浆乙酰化产物的影响,得出工艺条件为活化时间3 h、温度80℃、固液比1∶9;酯化时间2 h、温度50℃、催化剂用量2.50%以及反应摩尔比2.00的情况下,所得产物的不溶物含量较少,特性黏数较大,性能优良。

【Abstract】 The influence of activated and acetylaed technology on the production of acetylated wood pulp are investigated.The results show that under the conditions of activated time of 3 h,activated temperature of 80℃,amount of acid as 9 times to that of pulp,acetylated time of 2 h,acetylated temperature of 50℃,amount of sulfuric acid 2.50% and the molar rate of acetic anhydride as 2 times to that of the cellulose’s hydroxyl group,the product has good properties with less insoluble residues and fine intrinsic viscosity.

  • 【文献出处】 现代化工 ,Modern Chemical Industry , 编辑部邮箱 ,2009年S2期
  • 【分类号】TQ316.3
  • 【被引频次】4
  • 【下载频次】117
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