节点文献
二维网状有机锑对氨基苯乙酸酯的合成、表征及晶体结构研究(英文)
Synthesis,Characterization and Crystal Structure of A 2D Organoantimony Complex （C6H5）3Sb（O2CCH2C6H4NH2-p）2
【摘要】 The title complex bis(4-aminophenylacetate)triphenylantimony(V) has been synthesized by the reaction of triphenylantimony dibromide with 4-aminophenylacetic acid in 1∶2 molar ratio. The complex was characterized by elemental analysis,IR spectra,NMR (1H,13C) and X-ray diffraction crystal structure analysis. This complex crystallizes in the monoclinic system,space group C2/c with a=2.279 4(2) nm,b=0.957 10(10) nm,c=1.335 49(15) nm,β=93.781(2)°. The molecular structure adopts a distorted trigonal bipyramidal geometry around the antimony atom. In the crystal structure molecules are connected by intermolecular N-H …O hydrogen-bonding interactions forming a two-dimensional network structure. CCDC:726039.
【Abstract】 The title complex bis(4-aminophenylacetate)triphenylantimony(V) has been synthesized by the reaction of triphenylantimony dibromide with 4-aminophenylacetic acid in 1∶2 molar ratio. The complex was characterized by elemental analysis,IR spectra,NMR (1H,13C) and X-ray diffraction crystal structure analysis. This complex crystallizes in the monoclinic system,space group C2/c with a=2.279 4(2) nm,b=0.957 10(10) nm,c=1.335 49(15) nm,β=93.781(2)°. The molecular structure adopts a distorted trigonal bipyramidal geometry around the antimony atom. In the crystal structure molecules are connected by intermolecular N-H …O hydrogen-bonding interactions forming a two-dimensional network structure. CCDC:726039.
【Key words】 organoantimony carboxylate； 4-aminophenylacetic acid； synthesis； crystal structure；
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2009年08期
- 【分类号】O625.523
- 【被引频次】4
- 【下载频次】53