节点文献
三维配位聚合物[C4H12N2]3[PMo12O40]的合成、结构及其电化学性质（英文）
Synthesis, Structure and Electrochemical Properties of Three-Dimensional Complex [C4H12N2]3[PMo12O40]
【摘要】 The title compound [C4H12N2]3[PMo12O40] was synthesized from the hydrothermal reaction and charac- terized by IR, elemental analysis and X-ray signal crystal structural analysis. The crystal of the title complex belongs to trigonal space group R3c with a=1.788 62 nm, c=2.354 3 nm, and V=6.522 62 nm3, Z=6, R1=0.038 4, wR2 =0.102 0. The compound consisted of piperazine and PMo12O403 - , and the structure is extended to three dimensional framework owing to the hydrogen bond between the O atoms and N atoms. The bulk-modified carbon paste electrode (APM-CPE) using this compound as modifier shows a good electrocatalytic activity toward the oxidation of ascorbic acid(AA).
【Abstract】 The title compound [C4H12N2]3[PMo12O40] was synthesized from the hydrothermal reaction and charac- terized by IR, elemental analysis and X-ray signal crystal structural analysis. The crystal of the title complex belongs to trigonal space group R3c with a=1.788 62 nm, c=2.354 3 nm, and V=6.522 62 nm3, Z=6, R1=0.038 4, wR2 =0.102 0. The compound consisted of piperazine and PMo12O403 - , and the structure is extended to three dimensional framework owing to the hydrogen bond between the O atoms and N atoms. The bulk-modified carbon paste electrode (APM-CPE) using this compound as modifier shows a good electrocatalytic activity toward the oxidation of ascorbic acid(AA).
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2009年06期
- 【分类号】O634
- 【被引频次】2
- 【下载频次】94