节点文献
基于柔性硫醚与Cu2Br2单元二维配位聚合物的合成、结构和荧光性质（英文）
Synthesis,Structure and Photoluminescent Properties of the 2D Coordination Polymers Based on Cu2Br2 Unit with Flexible Thioether
【摘要】 A complex [Cu2Br2(L)2]n(1)(L=bis(2-pyrimidinylthio)methane)has been synthesized and structurally characterized.Complex 1 contains dinuclear Cu2Br2 units,which are linked by ditopic L to form a 2D layer structure with a 36-membered macrometallocycle.The adjacent layers are further connected through interpyrimidyl rings C-H … N and π-π interactions to give rise to a three-dimensional supramolecular structure.Complex 1 also displays strong green solid-state photoluminescence,due to metal-to-ligand charge-transfer(MLCT)at room temperature.CCDC:711434.
【Abstract】 A complex [Cu2Br2(L)2]n(1)(L=bis(2-pyrimidinylthio)methane)has been synthesized and structurally characterized.Complex 1 contains dinuclear Cu2Br2 units,which are linked by ditopic L to form a 2D layer structure with a 36-membered macrometallocycle.The adjacent layers are further connected through interpyrimidyl rings C-H … N and π-π interactions to give rise to a three-dimensional supramolecular structure.Complex 1 also displays strong green solid-state photoluminescence,due to metal-to-ligand charge-transfer(MLCT)at room temperature.CCDC:711434.
【Key words】 copper(Ⅰ) coordination polymer； flexible thioether； crystal structure； photoluminescence；
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2009年02期
- 【分类号】O627.12
- 【下载频次】98