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武汉市郊农田土壤中有机氯农药的残留分析

Residue analysis of organoohlorine pesticides in soil from Wuhan rural

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【作者】 金士威黎明廖涛惠阳徐盈

【Author】 JIN Shi-wei1,2,LI Ming1,LIAO Tao3,HUI Yang2,XU Ying(1.School of Chemical Engineering and Pharmacy,Wuhan Institute of Technology,Key Laboratory for Green ChemicalProcess of Ministry of Education,Wuhan 430074,China;2.State Key Laboratory of Freshwater Ecology and Biotechnology,Institute of Hydrobiology,Chinese Academy of Sciences,Wuhan 430072,China;3.Institute for Farm Products Processing and Nuclear-Agricultural Technology,Hubei Academy of Agricultural Sciences,Hubei Innovation Center of Agricultual Science and Technology,Wuhan 430064,China)

【机构】 武汉工程大学化工与制药学院绿色化工过程省部共建教育部重点实验室武汉中国科学院水生生物研究所淡水生态与生物技术国家重点实验室湖北省农业科技创新中心湖北省农业科学院农产品加工与核农技术研究所

【摘要】 通过采集武汉市郊农田表层土壤,用GC-ECD法分析了土壤中HCH(六六六)、DDT(滴滴涕)及其代谢物的残留情况.结果表明:HCH残留低于DDT,∑HCHs介于0.18~18.90 ng.g-1,平均值为1.97 ng.g-1,∑DDTs介于1.82~165.34 ng.g-1,平均值为31.41 ng.g-1;残留水平较高的是p,p′-DDE、p,p′-DDD和p,p′-DDT.部分表层土壤中的∑DDTs超出了中国土壤环境质量标准的自然背景值.初步分析结果表明武汉市郊土壤中HCH及DDT的含量处于低浓度水平.

【Abstract】 The residues of DDT and its metabolites(DDTs) and hexachlorocyclohexane isomers(HCHs) in topsoil from Wuhan Rural were analysed by GC-ECD method.The results showed the concentration of ∑HCHs and ∑DDTs in the soil ranged from 0.18—18.90 ng·g-1 and 1.82—165.34 ng·g-1 respectively,and the mean of them were 1.97 ng·g-1 and 31.41 ng·g-1,respectively.It was found that ∑DDTs concentrations in some samples(2 out of 11) exceeded the official Chinese norms for DDT.And the preliminary results revealed the concentrations of DDTs and HCHs were low in soils from Wuhan Rural.

【关键词】 DDTHCH土壤气相色谱
【Key words】 DDTHCHsoilgas chromatography
【基金】 科技部863项目(2006AA06Z424);湖北省教育厅青年基金(2004Q001);湖北省自然科学基金(2006ABA284)
  • 【文献出处】 武汉工程大学学报 ,Journal of Wuhan Institute of Technology , 编辑部邮箱 ,2009年07期
  • 【分类号】X592
  • 【被引频次】19
  • 【下载频次】263
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