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碳化硅陶瓷板上熔融煤灰侵蚀特性的实验研究

Experimental Investigation on Corrosion Characteristic of Melted Ash on SiC Based Refractory

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【作者】 裴晓冲陈彦菲陈冬林鄢晓忠叶昌

【Author】 PEI Xiao-chong1,CHEN Yan-fei1,CHEN Dong-lin1,YAN Xiao-zhong1,YE Chang2(1.School of Energy and Thermal Power Engineering,Changsha University of Science and Technology,Changsha 410076,China;2.School of Materials Science and Engineering,Changsha University of Science and Technology,Changsha 410076,China)

【机构】 长沙理工大学能源与动力工程学院长沙理工大学材料科学与工程学院

【摘要】 分别将0.2 g云贵和金竹山煤灰以相同的面积与厚度疏松散布在硅酸锆结合含铬SiC陶瓷板上获得多组煤灰/陶瓷板试样对,依次置于高温马弗炉中分别升温至1 250℃,1 350℃和1 450℃并恒温40 h;试样自然冷却后,对灰渣与陶瓷板进行扫描电镜(SEM)分析,然后将灰渣进行X射线衍射(XRD)检测。结果表明,温度对煤灰在SiC陶瓷板上的侵蚀有重要影响,且在相同温度下,SiC陶瓷板上云贵煤灰的熔融烧结现象比金竹山煤灰严重得多。当用此种材料作锅炉卫燃带时,对于云贵煤与金竹山煤,其表面温度应分别控制在1 250℃与1 350℃以下。

【Abstract】 Sample pairs of coal ash/refractory were prepared through spreading loosely 0.2 g ash of coal Yungui and Jinzhushan with identical area and thickness on SiC-based refractory board,which contains zirconium silicate and chromium oxide.Then the sample pairs were put into a high temperature muffle for 40 hours sintering at 1 250 ℃,1 350 ℃ and 1 450 ℃ respectively.After being cooled down naturally,microscopic morphology analysis of these sample pairs was conducted with a scanning electron microscopy(SEM) and then,the sintered coal ash was analyzed by a X-ray diffraction(XRD) apparatus.The results show that temperature in the muffle has great effect on corrosion of the melted ash on the SiC-based refractory and the corrosion by ash of coal Yungui is more severe than that of coal Jinzhushan and imply that,if the SiC-based refractory is used as the heat-insulating layer on waterwalls of furnaces firing coal Yungui and Jinzhushan, the surface temperature of the refractory should be controlled below 1 250 ℃and 1 350 ℃ respectively.

【关键词】 煤灰碳化硅侵蚀XRDSEM
【Key words】 coal ashSiCcorrosionXRDSEM
【基金】 国家自然科学基金(50576005);湖南省科技厅项目(05A016)
  • 【文献出处】 武汉理工大学学报 ,Journal of Wuhan University of Technology , 编辑部邮箱 ,2009年12期
  • 【分类号】TQ174.1
  • 【被引频次】2
  • 【下载频次】104
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