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Mg-Li合金熔炼反应的热力学分析及铸锭显微组织

Thermodynamic Analysis of Chemical Reaction in Melting Process of Mg-Li Alloy and Microstructure of Ingot

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【作者】 曹富荣丁桦李英龙陈彦博崔建忠

【Author】 Cao Furong1,Ding Hua1,Li Yinglong1,Chen Yanbo1,Cui Jianzhong2 (1.School of Materials and Metallurgy,Northeastern University,Shenyang,China; 2. Key Laboratory of Electromagnetic Processing of Materials,Ministry of Education,Northeastern University,Shenyang,China)

【机构】 东北大学材料与冶金学院东北大学材料电磁过程教育部重点实验室

【摘要】 采用LiCl与LiF质量比为3:1的熔剂覆盖和氩气保护,在铸铁坩埚中熔炼,在铜模中浇注制备了Mg-6.1Li、Mg-8.2Li、Mg-10.8Li合金铸锭,获得了满意的铸锭显微组织。化学反应热力学分析表明,石墨、MgO不适合作Mg-Li合金熔铸的工具材质,适合Mg-Li合金熔铸的工具材质是铸铁、低碳钢、Mo、Cu、SiC。对反应进行了热力学分析,与试验结果基本一致。

【Abstract】 Mg-6.1Li,Mg-8.2 Li and Mg-10.8Li,alloy ingots were prepared by melting in cast-iron crucible and casting in copper mould under the coverage of lithium chloride and lithium fluoride (LiCl:LiF=3:1) and the protection of argon,obtaining desirable ingot microstructure. Chemical reaction thermodynamic analysis reveals that graphite and magnesia are unsuitable as tool materials for melting and casting Mg-Li alloy,while cast iron,low carbon steel,Mo,copper and silicon carbide are suitable as tool materials. Thermodynamic analysis is basically consistent with the experimental results and relevant literatures.

【基金】 国家自然科学基金资助项目(50774023)
  • 【文献出处】 特种铸造及有色合金 ,Special Casting & Nonferrous Alloys , 编辑部邮箱 ,2009年09期
  • 【分类号】TG21
  • 【被引频次】4
  • 【下载频次】324
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