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高铁酸钾降解苯酚的GCMS分析

Analysis of Degradation Intermediates of Phenol with Potassium Ferrate by Gas Chromatography and Mass Spectrometry

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【作者】 邓子峰杨晓徐伟

【Author】 DENG Zifeng,YANG Xiao,XU Wei (Department of Chemistry,Tongji University,Shanghai 200092,China)

【机构】 同济大学化学系

【摘要】 采用蒸发、衍生化等方法分离、富集出高铁酸钾氧化降解苯酚的中间产物,利用气相色谱质谱联用仪(GC MS)定性分析出了对苯二酚、苯醌、联苯二酚和苯氧基苯酚以及草酸、顺丁烯二酸和反丁烯二酸等降解中间产物,并依此推测了高铁酸钾降解苯酚的主要途径.

【Abstract】 The phenol was oxidized by potassium ferrate.The intermediates were extracted from the degraded mixtures with vaporization,derivation,and ion-exchange methods and analyzed with gas chromatography and mass spectrometry(GCMS)techniques.Benzoquinone,hydroquinone,diaphenol,phenoxyl phenol,maleic acid,fumaric acid,and oxalic were determined.Based on the results,the degrading path of phenol was deduced.

  • 【文献出处】 同济大学学报(自然科学版) ,Journal of Tongji University(Natural Science) , 编辑部邮箱 ,2009年03期
  • 【分类号】X703
  • 【被引频次】19
  • 【下载频次】508
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